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Funding This work was supported by the Henan Provincial Breast Cancer Precision Prevention and Control Engineering Research Center (ZC20220050), the Henan Provincial Peoples Hospital23456 Talent Engineering Project (ZC23456026) and the study on the Effect and Mechanism of Macrophage-Derived Exosomes Loaded with Doxorubicin for Targeted Therapy of Triple-Negative Breast Cancer (ZC20220114)

Low ATP or mitochondrial stress Converting methionine to SAM requires ATP

1 H NMR (400 MHz, Chloroform-d) = 8.65 (dd, J = 4.8, 2.6 Hz, 1H), 8.047.93 (m, 2H), 7.83 (td, J = 7.7, 2.2 Hz, 1H), 7.74 (dd, J = 8.1, 2.6 Hz, 1H), 7.32 (p, J = 3.3 Hz, 1H), 7.026.91 (m, 2H), 4.15 (dt, J = 8.6, 3.9 Hz, 2H), 3.83 (dt, J = 8.5, 3.7 Hz, 2H), 2.03 (dt, J = 8.4, 3.9 Hz, 2H)

Glutathione also assists in enzymatic reactions and helps other antioxidants, like vitamin E, return to their active form to continue working as antioxidants