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"Discoloration of skin and urine after treatment with hydroxocobalamin for cyanide poisoning"

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It is not approved by the U.S

Multiple cycles cause cumulative damage through: Ice crystal formation physically disrupting peptide structure Concentration gradients during freezing causing localised pH changes Increased aggregation of peptide molecules during the thawing phase If accidental freezing occurs, thaw slowly in a refrigerator (not at room temperature or in warm water), inspect for cloudiness, and use within 7 days